A team of physicists and chemists has discovered a previously unknown way in which light interacts with matter, a finding that could lead to improved solar power systems, light-emitting diodes, semiconductor lasers and other technological advancements.
Kharintsev et al. found that photons can obtain substantial momentum, similar to that of electrons in solid materials, when confined to nanometer-scale spaces in silicon. Image credit: Kharintsev et al.
“Silicon is Earth’s second-most abundant element, and it forms the backbone of modern electronics,” said Dr. Dmitry Fishman, a chemist at the University of California, Irvine.
“However, being an indirect semiconductor, its utilization in optoelectronics has been hindered by poor optical properties.”
“While silicon does not naturally emit light in its bulk form, porous and nanostructured silicon can produce detectable light after being exposed to visible radiation.”
Scientists have been aware of this phenomenon for decades, but the precise origins of the illumination have been the subject of debate.
“In 1923, Arthur Compton discovered that gamma photons possessed sufficient momentum to strongly interact with free or bound electrons,” Dr. Fishman said.
“This helped prove that light had both wave and particle properties, a finding that led to Compton receiving the Nobel Prize in physics in 1927.”
“In our experiments, we showed that the momentum of visible light confined to nanoscale silicon crystals produces a similar optical interaction in semiconductors.”
An understanding of the origin of the interaction requires another trip back to the early 20th century.
In 1928, Indian physicist C.V. Raman, who won the 1930 Nobel Prize in physics, attempted to repeat the Compton experiment with visible light.
However, he encountered a formidable obstacle in the substantial disparity between the momentum of electrons and that of visible photons.
Despite this setback, Raman’s investigations into inelastic scattering in liquids and gases led to the revelation of what is now recognized as the vibrational Raman effect, and spectroscopy — a crucial method of spectroscopic studies of matter — has come to be known as Raman scattering.
“Our discovery of photon momentum in disordered silicon is due to a form of electronic Raman scattering,” University of California, Irvine’s Professor Eric Potma.
“But unlike conventional vibrational Raman, electronic Raman involves different initial and final states for the electron, a phenomenon previously only observed in metals.”
For their experiments, the researchers produced in their laboratory silicon glass samples that ranged in clarity from amorphous to crystal.
They subjected a 300-nm-thick silicon film to a tightly focused continuous-wave laser beam that was scanned to write an array of straight lines.
In areas where the temperature did not exceed 500 degrees Celsius, the procedure resulted in the formation of a homogenous cross-linked glass.
In areas where the temperature exceeded 500 degrees Celsius, a heterogeneous semiconductor glass was formed.
This light-foamed film allowed the scientists to observe how electronic, optical and thermal properties varied on the nanometer scale.
“This work challenges our understanding of light and matter interaction, underscoring the critical role of photon momenta,” Dr. Fishman said.
“In disordered systems, electron-photon momentum matching amplifies interaction — an aspect previously associated only with high-energy gamma-photons in classical Compton scattering.”
“Ultimately, our research paves the way to broaden conventional optical spectroscopies beyond their typical applications in chemical analysis, such as traditional vibrational Raman spectroscopy into the realm of structural studies — the information that should be intimately linked with photon momentum.”
“This newly realized property of light no doubt will open a new realm of applications in optoelectronics,” Professor Potma said.
“The phenomenon will boost the efficiency of solar energy conversion devices and light-emitting materials, including materials that were previously considered not suitable for light emission.”
This research is described in a paper in the journal ACS Nano.
_____
Sergey S. Kharintsev et al. 2024. Photon-Momentum-Enabled Electronic Raman Scattering in Silicon Glass. ACS Nano 18 (13): 9557-9565
>>> Read full article>>>
Copyright for syndicated content belongs to the linked Source : Sci-News.com – https://www.sci.news/physics/photon-momentum-silicon-12912.html
![Forest ecology cannot be reduced to arithmetic, says M.I. Varghese [Interview] – Mongabay-India](https://earth-news.info/wp-content/uploads/2025/12/328946-forest-ecology-cannot-be-reduced-to-arithmetic-says-mi-varghese-interview-mongabay-india-120x86.jpg)
